Intense Photoinduced Intervalence Charge Transfer in High‐Valent Iron Mixed Phenolate/Carbene Complexes

We report high‐valent iron complexes supported by N‐heterocyclic carbene (NHC)‐anchored, bis‐phenolate pincer ligands that undergo ligand‐to‐metal charge transfer (LMCT) upon photoexcitation. The resulting excited states – with a lifetime in the picosecond range – feature a ligand‐based, mixed‐valen...

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Detalles Bibliográficos
Autores principales: Cadranel, Alejandro, Gravogl, Lisa, Munz, Dominik, Meyer, Karsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401866/
https://www.ncbi.nlm.nih.gov/pubmed/35302682
http://dx.doi.org/10.1002/chem.202200269

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9401866/
https://www.ncbi.nlm.nih.gov/pubmed/35302682
http://dx.doi.org/10.1002/chem.202200269

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