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Novel Synthesis Methods of New Imidazole-Containing Coordination Compounds Tc(IV, V, VII)—Reaction Mechanism, Xrd and Hirshfeld Surface Analysis

In this work, we have proposed two new methods for the synthesis of [TcO(2)L(4)](+) (where L = imidazole (Im), methylimidazole (MeIm)) complexes using thiourea (Tu) and Sn(II) as the reducing agents. The main and by-products of the reactions were determined, and possible reaction mechanisms were pro...

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Detalles Bibliográficos
Autores principales: Volkov, Mikhail Alexandrovich, Novikov, Anton Petrovich, Grigoriev, Mikhail Semenovich, Fedoseev, Alexander Mikhailovich, German, Konstantin Eduardovich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9408894/
https://www.ncbi.nlm.nih.gov/pubmed/36012725
http://dx.doi.org/10.3390/ijms23169461