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The Chloronium Cation [(C(2)H(3))(2)Cl(+)] and Unsaturated C(4)-Carbocations with C=C and C≡C Bonds in Their Solid Salts and in Solutions: An H(1)/C(13) NMR and Infrared Spectroscopic Study

Solid salts of the divinyl chloronium (C(2)H(3))(2)Cl(+) cation (I) and unsaturated C(4)H(6)Cl(+) and C(4)H(7)(+) carbocations with the highly stable CHB(11)Hal(11)(−) anion (Hal=F, Cl) were obtained for the first time. At 120 °C, the salt of the chloronium cation decomposes, yielding a salt of the...

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Detalles Bibliográficos
Autores principales: Stoyanov, Evgenii S., Stoyanova, Irina V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9409342/
https://www.ncbi.nlm.nih.gov/pubmed/36012378
http://dx.doi.org/10.3390/ijms23169111