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Photocatalytic Isomerization of (E)-Anethole to (Z)-Anethole

Natural product (E)-anethole was isomerized to (Z)-anethole in a photocatalytic reaction. For this purpose, a self-designed cheap photoreactor was constructed. Among 11 photosensitizers (organo and metal complex compounds), Ir(p-tBu-ppy)(3) led to the highest conversion. Triplet energies of (E)- and...

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Detalles Bibliográficos
Autores principales: Korff, Marvin, Paulisch, Tiffany O., Glorius, Frank, Doltsinis, Nikos L., Wünsch, Bernhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9412280/
https://www.ncbi.nlm.nih.gov/pubmed/36014580
http://dx.doi.org/10.3390/molecules27165342