Mechanistic Insights into Ni(II)-Catalyzed Nonalternating Ethylene–Carbon Monoxide Copolymerization

[Image: see text] Polyethylene materials with in-chain-incorporated keto groups were recently enabled by nonalternating copolymerization of ethylene with carbon monoxide in the presence of Ni(II) phosphinephenolate catalysts. We elucidate the mechanism of this long-sought-for reaction by a combined...

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Detalles Bibliográficos
Autores principales: Voccia, Maria, Odenwald, Lukas, Baur, Maximilian, Lin, Fei, Falivene, Laura, Mecking, Stefan, Caporaso, Lucia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9413223/
https://www.ncbi.nlm.nih.gov/pubmed/35944187
http://dx.doi.org/10.1021/jacs.2c04563

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9413223/
https://www.ncbi.nlm.nih.gov/pubmed/35944187
http://dx.doi.org/10.1021/jacs.2c04563

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