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Effects of coordinating heteroatoms on molecular structure, thermodynamic stability and redox behavior of uranyl(vi) complexes with pentadentate Schiff-base ligands

Uranyl(vi) complexes with pentadentate N(3)O(2)-, N(2)O(3)- and N(2)O(2)S(1)-donating Schiff base ligands, tBu,MeO–saldien–X(2−) (X = NH, O and S), were synthesized and thoroughly characterized by (1)H NMR, IR, elemental analysis, and single crystal X-ray diffraction. The crystal structures of UO(2)...

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Detalles Bibliográficos
Autores principales: Takeyama, Tomoyuki, Takao, Koichiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9413499/
https://www.ncbi.nlm.nih.gov/pubmed/36128519
http://dx.doi.org/10.1039/d2ra04639c