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Thermally induced intra-molecular transformation and metalation of free-base porphyrin on Au(111) surface steered by surface confinement and ad-atoms

We investigated chemical transformations of a fluorinated free-base porphyrin, 5,10,15,20-tetrakis(4-fluorophenyl)-21,23H-porphyrin (2H-4FTPP) under a Au(111) surface confinement and including gold adatoms by using an experiment and density functional theory based first-principles calculations. Anne...

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Detalles Bibliográficos
Autores principales: Sen, Dipayan, Błoński, Piotr, de la Torre, Bruno, Jelínek, Pavel, Otyepka, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: RSC 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9417104/
https://www.ncbi.nlm.nih.gov/pubmed/36132418
http://dx.doi.org/10.1039/d0na00401d