Rhodium nanoparticles inside well-defined unimolecular amphiphilic polymeric nanoreactors: synthesis and biphasic hydrogenation catalysis

Rhodium nanoparticles (Rh NPs) embedded in different amphiphilic core-crosslinked micelle (CCM) latexes (RhNP@CCM) have been synthesized by [RhCl(COD)(TPP@CCM)] reduction with H(2) (TPP@CCM = core-anchored triphenylphosphine). The reduction rate depends on temperature, on the presence of base (NEt(3...

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Detalles Bibliográficos
Autores principales: Wang, Hui, Fiore, Ambra Maria, Fliedel, Christophe, Manoury, Eric, Philippot, Karine, Dell'Anna, Maria Michela, Mastrorilli, Piero, Poli, Rinaldo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: RSC 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9419193/
https://www.ncbi.nlm.nih.gov/pubmed/36134168
http://dx.doi.org/10.1039/d1na00028d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9419193/
https://www.ncbi.nlm.nih.gov/pubmed/36134168
http://dx.doi.org/10.1039/d1na00028d

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