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Optimisation of (1)H PMLG homonuclear decoupling at 60 kHz MAS to enable (15)N–(1)H through-bond heteronuclear correlation solid-state NMR spectroscopy
The Lee–Goldburg condition for homonuclear decoupling in (1)H magic-angle spinning (MAS) solid-state NMR sets the angle θ, corresponding to arctan of the ratio of the rf nutation frequency, ν(1), to the rf offset, to be the magic angle, θ(m), equal to tan(−1)(√2) = 54.7°. At 60 kHz MAS, we report en...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9429863/ https://www.ncbi.nlm.nih.gov/pubmed/35975627 http://dx.doi.org/10.1039/d2cp01041k |