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Photocatalytic CO(2) reduction sensitized by a special-pair mimic porphyrin connected with a rhenium(i) tricarbonyl complex
Zn porphyrins with an imidazolyl group at the meso position generate a highly stable porphyrin dimer by complementary coordination from the imidazolyl to the Zn ion in noncoordinating solvents such as chloroform, which mimics the natural special pair in photosynthesis. In this work, we have synthesi...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9430738/ https://www.ncbi.nlm.nih.gov/pubmed/36128228 http://dx.doi.org/10.1039/d2sc03251a |