Cargando…

Photocatalytic CO(2) reduction sensitized by a special-pair mimic porphyrin connected with a rhenium(i) tricarbonyl complex

Zn porphyrins with an imidazolyl group at the meso position generate a highly stable porphyrin dimer by complementary coordination from the imidazolyl to the Zn ion in noncoordinating solvents such as chloroform, which mimics the natural special pair in photosynthesis. In this work, we have synthesi...

Descripción completa

Detalles Bibliográficos
Autores principales: Kuramochi, Yusuke, Sato, Ren, Sakuma, Hiroki, Satake, Akiharu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9430738/
https://www.ncbi.nlm.nih.gov/pubmed/36128228
http://dx.doi.org/10.1039/d2sc03251a