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Aromatic heterobicycle-fused porphyrins: impact on aromaticity and excited state electron transfer leading to long-lived charge separation

A new synthetic method to fuse benzo[4,5]imidazo[2,1-a]isoindole to the porphyrin periphery at the β,β-positions has been developed, and its impact on the aromaticity and electronic structures is investigated. Reactivity investigation of the fused benzoimidazo-isoindole component reveals fluorescenc...

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Detalles Bibliográficos
Autores principales: Moss, Austen, Jang, Youngwoo, Arvidson, Jacob, Nesterov, Vladimir N., D'Souza, Francis, Wang, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431455/
https://www.ncbi.nlm.nih.gov/pubmed/36199634
http://dx.doi.org/10.1039/d2sc03238d