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A comprehensive understanding of carbon–carbon bond formation by alkyne migratory insertion into manganacycles

Migratory insertion (MI) is one of the most important processes underpinning the transition metal-catalysed formation of C–C and C–X bonds. In this work, a comprehensive model of MI is presented, based on the direct observation of the states involved in the coupling of alkynes with cyclometallated l...

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Detalles Bibliográficos
Autores principales: Hammarback, L. Anders, Eastwood, Jonathan B., Burden, Thomas J., Pearce, Callum J., Clark, Ian P., Towrie, Michael, Robinson, Alan, Fairlamb, Ian J. S., Lynam, Jason M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431456/
https://www.ncbi.nlm.nih.gov/pubmed/36199635
http://dx.doi.org/10.1039/d2sc02562k