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A comprehensive understanding of carbon–carbon bond formation by alkyne migratory insertion into manganacycles
Migratory insertion (MI) is one of the most important processes underpinning the transition metal-catalysed formation of C–C and C–X bonds. In this work, a comprehensive model of MI is presented, based on the direct observation of the states involved in the coupling of alkynes with cyclometallated l...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431456/ https://www.ncbi.nlm.nih.gov/pubmed/36199635 http://dx.doi.org/10.1039/d2sc02562k |