Mixed crystal of bis­(ammonium/oxonium) tetra­aqua-μ(3)-fluorido-dodeca­kis­(μ(2)-tri­fluoro­acetato)octa­hedro-hexa­ytterbiate(III) tetra­hydrate, [(NH(4))(1–x )(H(3)O)( x )](2)[Yb(6)F(8)(O(2)CCF(3))(12)(H(2)O)(4)]·4H(2)O (x = 1/4), containing a hexa­nuclear ytterbium(III) carboxyl­ate complex with face-capping fluoride ligands and comprising an unusual kind of substitutional disorder

The reaction of ytterbium metal with ammonium tri­fluoro­acetate in liquid ammonia resulted in a green substance comprising a substantial amount of ytterbium(II) tri­fluoro­acetate that is a useful precursor for the oxidative synthesis of the new ytterbium(III) compound, [(NH(4))(1–x )(H(3)O)( x )](...

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Detalles Bibliográficos
Autores principales: Morsbach, Florian, Frank, Walter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431779/
https://www.ncbi.nlm.nih.gov/pubmed/36072146
http://dx.doi.org/10.1107/S2056989022004790

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431779/
https://www.ncbi.nlm.nih.gov/pubmed/36072146
http://dx.doi.org/10.1107/S2056989022004790

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