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Incorporation of in situ generated 3,3′-(sulfanediyl)bis(1-methyl-1,3-imidazolidine-2-thione) into a one-dimensional Cu(I) coordination polymer with sulfur-bridged {Cu(I) (4)S(10)}( n ) central cores
The reaction of [Cu(CH(3)CN)(4)](BF(4)) with 1-methyl-1,3-imidazolidine-2-thione {SC(3)H(4)(NMe)NH}, under aerobic conditions at room temperature, yielded an unusual one-dimensional coordination polymer, namely, catena-poly[[[(1-methyl-1,3-imidazolidine-2-thione-κS)copper(I)]-μ-(1-methyl-1,3-imidaz...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9431798/ https://www.ncbi.nlm.nih.gov/pubmed/36072158 http://dx.doi.org/10.1107/S2056989022004911 |