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Generation and Reactivity of 1-Imidocarbenium Cations in the Friedel–Crafts-type Reaction
[Image: see text] Herein, we discuss the formation and reactivity of 1-imidocarbenium cations in Friedel–Crafts-type reaction between 1-imidoalkylphosphonium salts and arenes. The observed weakening of C(α)–P(+) bond is described qualitatively and quantitatively. The determination of rate constants...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9434785/ https://www.ncbi.nlm.nih.gov/pubmed/36061720 http://dx.doi.org/10.1021/acsomega.2c03930 |