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Enantioselective Cobalt-Catalyzed Hydroboration of Fluoroalkyl-Substituted Alkenes to Access Chiral Fluoroalkylboronates

[Image: see text] Selective defluoroborylation and asymmetric hydroboration reactions of fluoroalkyl-substituted terminal alkenes with pinacolborane (HBpin) have been developed with cobalt catalysts generated from Co(acac)(2) and bisphosphine ligands. A variety of fluoroalkyl-substituted terminal al...

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Detalles Bibliográficos
Autores principales: Hu, Ming, Tan, Boon Beng, Ge, Shaozhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9434995/
https://www.ncbi.nlm.nih.gov/pubmed/35953077
http://dx.doi.org/10.1021/jacs.2c06488