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Dual electronic effects achieving a high-performance Ni(II) pincer catalyst for CO(2) photoreduction in a noble-metal-free system
A carbazolide-bis(NHC) Ni(II) catalyst (1; NHC, N-heterocyclic carbene) for selective CO(2) photoreduction was designed herein by a one-stone-two-birds strategy. The extended π-conjugation and the strong σ/π electron-donation characteristics (two birds) of the carbazolide fragment (one stone) lead t...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
National Academy of Sciences
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9436338/ https://www.ncbi.nlm.nih.gov/pubmed/35998222 http://dx.doi.org/10.1073/pnas.2119267119 |