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Dual electronic effects achieving a high-performance Ni(II) pincer catalyst for CO(2) photoreduction in a noble-metal-free system

A carbazolide-bis(NHC) Ni(II) catalyst (1; NHC, N-heterocyclic carbene) for selective CO(2) photoreduction was designed herein by a one-stone-two-birds strategy. The extended π-conjugation and the strong σ/π electron-donation characteristics (two birds) of the carbazolide fragment (one stone) lead t...

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Detalles Bibliográficos
Autores principales:	Huang, Hai-Hua, Zhang, Ji-Hong, Dai, Miao, Liu, Lianglin, Ye, Zongren, Liu, Jiahao, Zhong, Di-Chang, Wang, Jia-Wei, Zhao, Cunyuan, Ke, Zhuofeng
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	National Academy of Sciences 2022
Materias:	Physical Sciences
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9436338/ https://www.ncbi.nlm.nih.gov/pubmed/35998222 http://dx.doi.org/10.1073/pnas.2119267119

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