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Copper-catalyzed radical trans-selective hydroboration of ynamides with N-heterocyclic carbene boranes

Vinylboron compounds are important compounds in organic chemistry and biology. In this communication, we developed a copper(I)-catalyzed, highly regio- and stereoselective radical trans-hydroboration of ynamides with N-heterocyclic carbene (NHC)-ligated borane is reported, which leads to a series of...

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Detalles Bibliográficos
Autores principales: Wang, Kefeng, Yu, Qingzhen, Mao, Wenli, Zheng, Yuxin, Xu, Jing, Wang, Yukun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9440302/
https://www.ncbi.nlm.nih.gov/pubmed/36065185
http://dx.doi.org/10.1016/j.isci.2022.104977