Boron-Catalyzed, Diastereo- and Enantioselective Allylation of Ketones with Allenes

[Image: see text] The diastereo- and enantioselective allylation of ketones remains a synthetic challenge, with transition metal catalysis offering the most applied methods. Here, a boron-catalyzed allylation of ketones with allenes is presented. Excellent yield, regioselectivity, and diastereoselec...

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Detalles Bibliográficos
Autores principales: Nicholson, Kieran, Peng, Yuxuan, Llopis, Natalia, Willcox, Dominic R., Nichol, Gary S., Langer, Thomas, Baeza, Alejandro, Thomas, Stephen P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9442582/
https://www.ncbi.nlm.nih.gov/pubmed/36082052
http://dx.doi.org/10.1021/acscatal.2c03158

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9442582/
https://www.ncbi.nlm.nih.gov/pubmed/36082052
http://dx.doi.org/10.1021/acscatal.2c03158

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