Synthesis of Tetrahydroazepines through Silyl Aza-Prins Cyclization Mediated by Iron(III) Salts

[Image: see text] A new methodology for the synthesis of seven-membered unsaturated azacycles (tetrahydroazepines) was developed. It is based on the powerful aza-Prins cyclization in combination with the Peterson-type elimination reaction. In a single reaction step, a C–N, C–C bond and an endocyclic...

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Detalles Bibliográficos
Autores principales: Sinka, Victoria, Fernández, Israel, Padrón, Juan I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9442639/
https://www.ncbi.nlm.nih.gov/pubmed/35977416
http://dx.doi.org/10.1021/acs.joc.2c01396

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9442639/
https://www.ncbi.nlm.nih.gov/pubmed/35977416
http://dx.doi.org/10.1021/acs.joc.2c01396

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