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Photocatalytic Reduction of CO(2) to CO in Aqueous Solution under Red-Light Irradiation by a Zn-Porphyrin-Sensitized Mn(I) Catalyst

[Image: see text] This work demonstrates photocatalytic CO(2) reduction by a noble-metal-free photosensitizer-catalyst system in aqueous solution under red-light irradiation. A water-soluble Mn(I) tricarbonyl diimine complex, [MnBr(4,4′-{Et(2)O(3)PCH(2)}(2)-2,2′-bipyridyl)(CO)(3)] (1), has been full...

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Detalles Bibliográficos
Autores principales: Shipp, James, Parker, Simon, Spall, Steven, Peralta-Arriaga, Samantha L., Robertson, Craig C., Chekulaev, Dimitri, Portius, Peter, Turega, Simon, Buckley, Alastair, Rothman, Rachael, Weinstein, Julia A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9446891/
https://www.ncbi.nlm.nih.gov/pubmed/35960651
http://dx.doi.org/10.1021/acs.inorgchem.2c00091