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Synthesis and Functionalization of Challenging meso-Substituted Aryl Bis-pocket Porphyrins Accessed via Suzuki–Miyaura Cross-Coupling

[Image: see text] Herein we report an investigation into the synthesis, metalation, and functionalization of bis-pocket porphyrins using the Suzuki–Miyaura cross-coupling reaction. Steric limitations to accessing bis-pocket porphyrins were overcome by using this Pd-catalyzed C–C-bond-forming strateg...

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Detalles Bibliográficos
Autores principales: Droege, Daniel G., Parker, A. Leila, Milligan, Griffin M., Jenkins, Robert, Johnstone, Timothy C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9447288/
https://www.ncbi.nlm.nih.gov/pubmed/35976791
http://dx.doi.org/10.1021/acs.joc.2c01538