Study of the β-oxygen effect in the Barton–McCombie reaction for the total synthesis of (4R,5R)-4-hydroxy-γ-decalactone (Japanese orange fly lactone): a carbohydrate based approach

Efficient and facile synthesis of Japanese orange fly lactone (1) was achieved from a commercially available d-glucose by investigating the Barton–McCombie reaction with furanose anomeric isomers (12α, β) with an overall yield of 12.6%. During the course of this synthesis, the β-oxygen effect was di...

Descripción completa

Detalles Bibliográficos
Autores principales: Desireddi, Janardana Reddi, Rao, Mora Mallikarjuna, Murahari, Kiran Kumar, Nimmareddy, Rajashekar Reddy, Mothe, Thirupathi, Lingala, Arun Kumar, Maiti, Bhimcharan, Manchal, Ravinder
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9449999/
https://www.ncbi.nlm.nih.gov/pubmed/36199353
http://dx.doi.org/10.1039/d2ra04531a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9449999/
https://www.ncbi.nlm.nih.gov/pubmed/36199353
http://dx.doi.org/10.1039/d2ra04531a

Ejemplares similares