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Homoatomic cations: From [P(5)](+) to [P(9)](+)

Recent synthetic approaches to a series of [P(9)]X salts (X = [F{Al(OR(F))(3)}(2)], [Al(OR(F))(4)], and (R(F) = C(CF(3))(3)); Ga(2)Cl(7)) overcome limitations in classical synthesis methods that proved unsuitable for phosphorus cations. These salts contain the homopolyatomic cation [P(9)](+) via (I)...

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Detalles Bibliográficos
Autores principales: Frötschel-Rittmeyer, Julia, Holthausen, Michael, Friedmann, Christian, Röhner, David, Krossing, Ingo, Weigand, Jan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9451154/
https://www.ncbi.nlm.nih.gov/pubmed/36070385
http://dx.doi.org/10.1126/sciadv.abq8613