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Scalable, Chemoselective Nickel Electrocatalytic Sulfinylation of Aryl Halides with SO(2)

Simple access to aryl sulfinates from aryl iodides and bromides is reported using an inexpensive Ni‐electrocatalytic protocol. The reaction exhibits a broad scope, uses stock solution of simple SO(2) as sulfur source, and can be scaled up in batch and recycle flow settings. The limitations of this r...

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Detalles Bibliográficos
Autores principales: Lou, Terry Shing‐Bong, Kawamata, Yu, Ewing, Tamara, Correa‐Otero, Guillermo A., Collins, Michael R., Baran, Phil S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9452475/
https://www.ncbi.nlm.nih.gov/pubmed/35819400
http://dx.doi.org/10.1002/anie.202208080