Optimized Asymmetric Synthesis of Umuravumbolide

[Image: see text] Herein, the asymmetric synthesis of umuravumbolide (1) is described. The new approach features highly stereoselective transformations (dr ≥ 95:5) to install both stereocenters and the Z olefin, which involve a new radical alkylation, an Ando olefination, and a Krische allylation on...

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Detalles Bibliográficos
Autores principales: Pérez-Palau, Marina, Balaguer-Garcia, Eduard, Romea, Pedro, Urpí, Fèlix
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9453790/
https://www.ncbi.nlm.nih.gov/pubmed/36092614
http://dx.doi.org/10.1021/acsomega.2c02304

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9453790/
https://www.ncbi.nlm.nih.gov/pubmed/36092614
http://dx.doi.org/10.1021/acsomega.2c02304

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