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Optimized Asymmetric Synthesis of Umuravumbolide
[Image: see text] Herein, the asymmetric synthesis of umuravumbolide (1) is described. The new approach features highly stereoselective transformations (dr ≥ 95:5) to install both stereocenters and the Z olefin, which involve a new radical alkylation, an Ando olefination, and a Krische allylation on...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9453790/ https://www.ncbi.nlm.nih.gov/pubmed/36092614 http://dx.doi.org/10.1021/acsomega.2c02304 |