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Dinitrogen Binding and Activation: Bonding Analyses of Stable V(III/I)–N(2)–V(III/I) Complexes by the EDA–NOCV Method from the Perspective of Vanadium Nitrogenase
[Image: see text] The FeVco cofactor of nitrogenase (VFe(7)S(8)(CO(3))C) is an alternative in the molybdenum (Mo)-deficient free soil living azotobacter vinelandii. The rate of N(2) reduction to NH(3) by FeVco is a few times higher than that by FeMoco (MoFe(7)S(9)C) at low temperature. It provides a...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9453968/ https://www.ncbi.nlm.nih.gov/pubmed/36092593 http://dx.doi.org/10.1021/acsomega.2c04472 |