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Synthesis and Characterization of Phosphinecarboxamide and Phosphinecarbothioamide, and Their Complexation with Palladium(II) Complex †

Reactions of isocyanates/isothiocyanates with primary and secondary phosphines without solvent at room temperature afforded phosphinecarboxamide/phosphinecarbothioamide, respectively, in excellent yields. Furthermore, palladium complex Pd(COD)Cl(2) was allowed to react with Ph(2)PC(O)NHPh (1a) to af...

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Detalles Bibliográficos
Autores principales: Itazaki, Masumi, Okabayashi, Kento, Matsutani, Takanari, Nochida, Tomoya, Moriuchi, Toshiyuki, Nakazawa, Hiroshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9457633/
https://www.ncbi.nlm.nih.gov/pubmed/36080329
http://dx.doi.org/10.3390/molecules27175564