Synthesis of a Chiral 3,6T22-Zn-MOF with a T-Shaped Bifunctional Pyrazole-Isophthalate Ligand Following the Principles of the Supramolecular Building Layer Approach

The metal–organic framework (MOF) [Zn(Isa-az-tmpz)]·~1–1.5 DMF with the novel T-shaped bifunctional linker 5-(2-(1,3,5-trimethyl-1H-pyrazol-4-yl)azo)isophthalate (Isa-az-tmpz) was obtained as a conglomerate of crystals with varying degrees of enantiomeric excess in the chiral tetragonal space groups...

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Detalles Bibliográficos
Autores principales: Woschko, Dennis, Millan, Simon, Ceyran, Muhammed-Ali, Oestreich, Robert, Janiak, Christoph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9457947/
https://www.ncbi.nlm.nih.gov/pubmed/36080142
http://dx.doi.org/10.3390/molecules27175374

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9457947/
https://www.ncbi.nlm.nih.gov/pubmed/36080142
http://dx.doi.org/10.3390/molecules27175374

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