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Lewis Acid-Induced Dinitrogen Cleavage in an Anionic Side-on End-on Bound Dinitrogen Diniobium Hydride Complex
The side-on end-on dinitrogen hydride complex [{Na(dme)}(2){(O(3))Nb}(2)(μ-η(1):η(2)-N(2))(μ-H)(2)] (3-Na, [O(3)](3−) = [(3,5-(t)Bu(2)-2-O-C(6)H(2))(3)CH](3−)) was observed to undergo facile elimination of H(2) and cleavage of the N–N bond in the presence of 9-borabicyclo[3.3.1]nonane (9-BBN), AlMe(...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9457992/ https://www.ncbi.nlm.nih.gov/pubmed/36080319 http://dx.doi.org/10.3390/molecules27175553 |