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Slurry Homopolymerization of Ethylene Using Thermostable α-Diimine Nickel Catalysts Covalently Linked to Silica Supports via Substituents on Acenaphthequinone-Backbone

Four supported α-diimine nickel(II) catalysts covalently linked to silica via hydroxyl functionality on α-diimine acenaphthequinone-backbone were prepared and used in slurry polymerizations of ethylene to produce branched polyethylenes. The catalytic activities of these still reached 10(6) g/molNi·h...

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Detalles Bibliográficos
Autores principales: Zong, Kening, Hou, Yanhui, Zhao, Xiaobei, Sun, Yali, Liu, Binyuan, Yang, Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9459716/
https://www.ncbi.nlm.nih.gov/pubmed/36080759
http://dx.doi.org/10.3390/polym14173684