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New Approach to the Detection of Short-Lived Radical Intermediates

[Image: see text] We report a new general method for trapping short-lived radicals, based on a homolytic substitution reaction S(H)2′. This departure from conventional radical trapping by addition or radical–radical cross-coupling results in high sensitivity, detailed structural information, and gen...

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Detalles Bibliográficos
Autores principales: Williams, Peter J. H., Boustead, Graham A., Heard, Dwayne E., Seakins, Paul W., Rickard, Andrew R., Chechik, Victor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9460783/
https://www.ncbi.nlm.nih.gov/pubmed/36001076
http://dx.doi.org/10.1021/jacs.2c03618