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Poly[octacarbonylheptakis(tetrahydrofuran)diironmanganesedisodium(2 Mn—Fe)]
The reaction of Na(2)Fe(CO)(4) with an excess of MnCl(2) in tetrahydrofuran (THF) produced {Fe(2)Mn(C(4)H(8)O)(2)Na(2)(C(4)H(8)O)(5)(CO)(8)]( n ) or C(36)H(56)Fe(2)MnNa(2)O(15). The compound is a xenophilic dianion with short iron–manganese bond lengths of 2.6274 (10) and 2.6294 (10) Å. The sodium...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462363/ https://www.ncbi.nlm.nih.gov/pubmed/36339454 http://dx.doi.org/10.1107/S2414314621008452 |