Poly[octa­carbonyl­heptakis­(tetra­hydro­furan)­diironmanganesedisodium(2 Mn—Fe)]

The reaction of Na(2)Fe(CO)(4) with an excess of MnCl(2) in tetra­hydro­furan (THF) produced {Fe(2)Mn(C(4)H(8)O)(2)Na(2)(C(4)H(8)O)(5)(CO)(8)]( n ) or C(36)H(56)Fe(2)MnNa(2)O(15). The compound is a xenophilic dianion with short iron–manganese bond lengths of 2.6274 (10) and 2.6294 (10) Å. The sodium...

Descripción completa

Detalles Bibliográficos
Autores principales: Harakas, George N., Whittlesey, Bruce R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462363/
https://www.ncbi.nlm.nih.gov/pubmed/36339454
http://dx.doi.org/10.1107/S2414314621008452
Descripción
Sumario:The reaction of Na(2)Fe(CO)(4) with an excess of MnCl(2) in tetra­hydro­furan (THF) produced {Fe(2)Mn(C(4)H(8)O)(2)Na(2)(C(4)H(8)O)(5)(CO)(8)]( n ) or C(36)H(56)Fe(2)MnNa(2)O(15). The compound is a xenophilic dianion with short iron–manganese bond lengths of 2.6274 (10) and 2.6294 (10) Å. The sodium cations of the dianion are coordinated to THF ligands and have isocarbonyl inter­actions forming a polymeric (two-dimensional) structure in the crystal. One of the THF mol­ecules was modeled with the carbon atoms being statistically disordered. [Image: see text]

Ejemplares similares