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Probing the origin and stability of bivalency in copper based porous coordination network and its application for H(2)S gas capture
A bivalent Cu(I,II) metal–organic framework (MOF) based on the 4,4′,4″-s-Triazine-2,4,6-triyl-tribenzoate linker was synthesized via a solvothermal method. The MOF possessed 43.8% of the Cu sites as Cu(+) with a surface area of 1257 m(2) g(−1). The detailed spectroscopic analysis confirmed dimethylf...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9470748/ https://www.ncbi.nlm.nih.gov/pubmed/36100662 http://dx.doi.org/10.1038/s41598-022-19808-y |