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Probing the origin and stability of bivalency in copper based porous coordination network and its application for H(2)S gas capture

A bivalent Cu(I,II) metal–organic framework (MOF) based on the 4,4′,4″-s-Triazine-2,4,6-triyl-tribenzoate linker was synthesized via a solvothermal method. The MOF possessed 43.8% of the Cu sites as Cu(+) with a surface area of 1257 m(2) g(−1). The detailed spectroscopic analysis confirmed dimethylf...

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Detalles Bibliográficos
Autores principales: Gupta, Nishesh Kumar, Kim, Eun Ji, Bae, Jiyeol, Kim, Kwang Soo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9470748/
https://www.ncbi.nlm.nih.gov/pubmed/36100662
http://dx.doi.org/10.1038/s41598-022-19808-y