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Simple yttrium salts as highly active and controlled catalysts for the atom-efficient synthesis of high molecular weight polyesters

The ring-opening copolymerization (ROCOP) of epoxides and cyclic anhydrides is a promising route to sustainable aliphatic polyesters with diverse mechanical and thermal properties. Here, simple yttrium chloride salts (YCl(3)THF(3.5) and YCl(3)·6H(2)O), in combination with a bis(triphenylphosphoranyl...

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Detalles Bibliográficos
Autores principales: Wood, Zachary A., Assefa, Mikiyas K., Fieser, Megan E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9473511/
https://www.ncbi.nlm.nih.gov/pubmed/36277642
http://dx.doi.org/10.1039/d2sc02745c