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Acid-base-induced fac → mer isomerization of luminescent iridium(iii) complexes
Luminescent Ir(C^N)(3) complexes (C^N = cyclometalated arylpyridine ligand) exist in the form of two stable isomers with distinct photophysical and electrochemical properties: fac and mer. Herein, we show that fac-Ir(C^N)(3) complexes can be converted into the thermodynamically less stable mer forms...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9473533/ https://www.ncbi.nlm.nih.gov/pubmed/36277648 http://dx.doi.org/10.1039/d2sc02808e |