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Acid-base-induced fac → mer isomerization of luminescent iridium(iii) complexes

Luminescent Ir(C^N)(3) complexes (C^N = cyclometalated arylpyridine ligand) exist in the form of two stable isomers with distinct photophysical and electrochemical properties: fac and mer. Herein, we show that fac-Ir(C^N)(3) complexes can be converted into the thermodynamically less stable mer forms...

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Detalles Bibliográficos
Autores principales:	Yu. Gitlina, Anastasia, Fadaei-Tirani, Farzaneh, Ruggi, Albert, Plaice, Carolina, Severin, Kay
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9473533/ https://www.ncbi.nlm.nih.gov/pubmed/36277648 http://dx.doi.org/10.1039/d2sc02808e

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