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Ligand-enabled oxidation of gold(i) complexes with o-quinones

Chelating P^P and hemilabile P^N ligands were found to trigger the oxidation of Au(i) complexes by o-benzoquinones. The ensuing Au(iii) catecholate complexes have been characterized by NMR spectroscopy, single crystal X-ray diffraction and X-ray absorption spectroscopy. They adopt tetracoordinate sq...

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Detalles Bibliográficos
Autores principales: Szalóki, György, Babinot, Julien, Martin-Diaconescu, Vlad, Mallet-Ladeira, Sonia, García-Rodeja, Yago, Miqueu, Karinne, Bourissou, Didier
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9473537/
https://www.ncbi.nlm.nih.gov/pubmed/36277619
http://dx.doi.org/10.1039/d2sc03724f