Site-Selective Dehydroxy-Chlorination of Secondary Alcohols in Unprotected Glycosides

[Image: see text] To circumvent protecting groups, the site-selective modification of unprotected glycosides is intensively studied. We show that site-selective oxidation, followed by treatment of the corresponding trityl hydrazone with tert-butyl hypochlorite and a H atom donor provides an effectiv...

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Detalles Bibliográficos
Autores principales: Zhang, Ji, Reintjens, Niels R. M., Dhineshkumar, Jayaraman, Witte, Martin D., Minnaard, Adriaan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490796/
https://www.ncbi.nlm.nih.gov/pubmed/35848103
http://dx.doi.org/10.1021/acs.orglett.2c01992

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490796/
https://www.ncbi.nlm.nih.gov/pubmed/35848103
http://dx.doi.org/10.1021/acs.orglett.2c01992

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