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Site-Selective Dehydroxy-Chlorination of Secondary Alcohols in Unprotected Glycosides
[Image: see text] To circumvent protecting groups, the site-selective modification of unprotected glycosides is intensively studied. We show that site-selective oxidation, followed by treatment of the corresponding trityl hydrazone with tert-butyl hypochlorite and a H atom donor provides an effectiv...
Autores principales: | Zhang, Ji, Reintjens, Niels R. M., Dhineshkumar, Jayaraman, Witte, Martin D., Minnaard, Adriaan J. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490796/ https://www.ncbi.nlm.nih.gov/pubmed/35848103 http://dx.doi.org/10.1021/acs.orglett.2c01992 |
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