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Low-Valent Molybdenum PNP Pincer Complexes as Catalysts for the Semihydrogenation of Alkynes

[Image: see text] Low-valent molybdenum PNP pincer complexes were studied as catalysts for the semihydrogenation of alkynes. For that purpose, tBu-substituted PNP complexes PNP(tBu)Mo(CO)(2) (6a) and PNP(tBu)Mo(CO)(3) (6c) and the NNP complex NNP(iPr)Mo(CO)(2)(PPh(3)) ((rac)-7) were synthesized and...

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Detalles Bibliográficos
Autores principales: Both, Niklas F., Spannenberg, Anke, Junge, Kathrin, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490815/
https://www.ncbi.nlm.nih.gov/pubmed/36156902
http://dx.doi.org/10.1021/acs.organomet.1c00709