Copper(I)-Catalyzed Synthesis of Unsymmetrical All-Carbon Bis-Quaternary Centers at the Opposing α-Carbons of Cyclohexanones

[Image: see text] We describe a new synthetic reaction that generates all-carbon bis-quaternary centers at the opposing side of α-carbons in cyclohexanone with four different substituents in a controlled manner. Catalyzed by Cu(MeCN)(4)BF(4) salt, this chemistry is proposed to proceed via an interme...

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Detalles Bibliográficos
Autores principales: Malone, Joshua A., Philkhana, Satish Chandra, Stepherson, Jacob R., Badmus, Fatimat O., Fronczek, Frank R., Kartika, Rendy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490817/
https://www.ncbi.nlm.nih.gov/pubmed/35767696
http://dx.doi.org/10.1021/acs.orglett.2c01890

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490817/
https://www.ncbi.nlm.nih.gov/pubmed/35767696
http://dx.doi.org/10.1021/acs.orglett.2c01890

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