Gold-Catalyzed Regioselective Synthesis of Crowded Cyclopentadienes by Migratory Cycloisomerization of Vinylallenes

[Image: see text] We report the regioselective synthesis of silyl-substituted cyclopentadienyl esters through gold-catalyzed migratory cycloisomerization of silyl-substituted vinylallenes. This transformation is proposed to proceed through a perfectly orchestrated sequence of events including Nazaro...

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Detalles Bibliográficos
Autores principales: Bernardo, Olaya, González, Javier, Borge, Javier, López, Luis A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490818/
https://www.ncbi.nlm.nih.gov/pubmed/35819017
http://dx.doi.org/10.1021/acs.orglett.2c02035

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490818/
https://www.ncbi.nlm.nih.gov/pubmed/35819017
http://dx.doi.org/10.1021/acs.orglett.2c02035

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