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Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)
[Image: see text] We report the synthesis and characterization of uranium(IV) and thorium(IV) mesoionic carbene complexes [An{N(SiMe(3))(2)}(2)(CH(2)SiMe(2)NSiMe(3)){MIC}] (An = U, 4U and Th, 4Th; MIC = {CN(Me)C(Me)N(Me)CH}), which represent rare examples of actinide mesoionic carbene linkages and t...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490841/ https://www.ncbi.nlm.nih.gov/pubmed/36157256 http://dx.doi.org/10.1021/acs.organomet.2c00120 |