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Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)

[Image: see text] We report the synthesis and characterization of uranium(IV) and thorium(IV) mesoionic carbene complexes [An{N(SiMe(3))(2)}(2)(CH(2)SiMe(2)NSiMe(3)){MIC}] (An = U, 4U and Th, 4Th; MIC = {CN(Me)C(Me)N(Me)CH}), which represent rare examples of actinide mesoionic carbene linkages and t...

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Detalles Bibliográficos
Autores principales:	Seed, John A., Vondung, Lisa, Adams, Ralph W., Wooles, Ashley J., Lu, Erli, Liddle, Stephen T.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490841/ https://www.ncbi.nlm.nih.gov/pubmed/36157256 http://dx.doi.org/10.1021/acs.organomet.2c00120

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