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Olefination with Sulfonyl Halides and Esters: Synthesis of Unsaturated Sulfonyl Fluorides

[Image: see text] Methanedisulfonyl fluoride, CH(2)(SO(2)F)(2), transforms aromatic aldehydes into β-arylethenesulfonyl fluorides, useful substrates for the SuFEx “click”-type transformations. The reaction mimics mechanism of the Horner–Wadsworth–Emmons olefination, which runs via addition of the ca...

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Detalles Bibliográficos
Autores principales: Tryniszewski, Michał, Basiak, Dariusz, Barbasiewicz, Michał
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490844/
https://www.ncbi.nlm.nih.gov/pubmed/35653711
http://dx.doi.org/10.1021/acs.orglett.2c01604