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Olefination with Sulfonyl Halides and Esters: Synthesis of Unsaturated Sulfonyl Fluorides
[Image: see text] Methanedisulfonyl fluoride, CH(2)(SO(2)F)(2), transforms aromatic aldehydes into β-arylethenesulfonyl fluorides, useful substrates for the SuFEx “click”-type transformations. The reaction mimics mechanism of the Horner–Wadsworth–Emmons olefination, which runs via addition of the ca...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490844/ https://www.ncbi.nlm.nih.gov/pubmed/35653711 http://dx.doi.org/10.1021/acs.orglett.2c01604 |